Complex equilibrium study of some hydroxyl aromatic lignds with beryllium ion

Santoso, Shella Permatasari and Angkawijaya, Artik Elisa and Soetaredjo, Felycia Edi and Ismadji, Suryadi and Yi-Hsu, Ju (2015) Complex equilibrium study of some hydroxyl aromatic lignds with beryllium ion. Journal of Molecular Liquids, 212. pp. 524-531. ISSN 0167-7322

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Abstract

Equilibrium studies of beryllium with 2,3- dihydroxybenzoic acid, 3,4-dihydroxybenzoic acid and gallic acid in an aqueous solution at 310.15 K, an ionic strength of 0.15 mol•dm-3 NaCl and pH 2.5 to 11.0 were investigated by the pH-potentiometric method. Stability constants of the complexes were determined by HyperQuad 2008 and presented as logβ. Contributing binding sites of these ligands were evaluated by comparing its logβ with some structurally related ligands such as catechol and salicylic acid. Spectrophotometric measurements were done to confirm the formation of thecomplex species. Geometry optimization and frequency analysis of the complexes were performed by using Gaussian09W program to verify the contributing binding sites. The results indicate that the ability of ligands in preventing the hydrolysis of Be2+ follows the order: 3,4-dihydroxybenzoic acid >2,3-dihydroxybenzoic acid>gallic acid

Item Type: Article
Uncontrolled Keywords: Beryllium Beryllium complex Hydroxy aromatic ligand Potentiometric Stability constan
Subjects: Engineering
Engineering > Chemical Engineering
Divisions: Faculty of Engineering > Chemical Engineering Study Program
Depositing User: Suryadi. Ismadji
Date Deposited: 24 May 2017 08:58
Last Modified: 19 Jul 2018 08:46
URI: http://repository.wima.ac.id/id/eprint/10796

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