Ammonia removal from water using sodium hydroxide modified zeolite mordenite

Soetardji, Jennifer Pieter and Claudia, Jeannete Cindy and Yi-Hsu, Ju and Hriljac, Joseph A. and Tzu-Yu, Chen and Soetaredjo, Felycia Edi and Santoso, Shella Permatasari and Kurniawan, Alfin and Ismadji, Suryadi (2015) Ammonia removal from water using sodium hydroxide modified zeolite mordenite. RSC Advances, 5 (102). pp. 83689-83699. ISSN 2046-2069

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Official URL: http://dx.doi.org/10.1039/c5ra15419g

Abstract

Natural and modifyed mordenite zeolites were used to remove ammonium ions from aqueous solution and Koi pond water. The zeolite modification was conducted using sodium hydroxide solutions of different strengths at 75C for 24 h. Langmuir, Freundlich, Sips, and Toth equations with their temperature dependent forms were used to represent the adsorption equilibria data. The Langmuir and its temperature dependent forms could represent the data better than the other models. The pseudo first order model has better performance than the pseudo-second order model in correlatingthe adsorption kinetic data. The controlling mechanism of the adsorption of NH4 + from aqueous solution onto the natural zeolite and the one treated with 6 M sodium hydroxide solution was dominated by physical adsorption. The competition with other ions occurred through different reaction mechanisms so it decreases the removal efficiency of ammonium ions by the zeolites. For the treated zeolite, the removal efficiency decreased from 81% to 66.9%. A Thomas model can represent the experimental data for both adsorption of ammonia from aqueous solution or from Koi pond water.

Item Type: Article
Subjects: Engineering > Chemical Engineering
Divisions: Faculty of Engineering > Chemical Engineering Study Program
Depositing User: Suryadi. Ismadji
Date Deposited: 13 Jul 2016 08:00
Last Modified: 11 Oct 2018 03:39
URI: http://repository.wima.ac.id/id/eprint/4171

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