Santoso, Shella Permatasari, Angkawijaya, Artik Elisa, Ju, Yi-Hsu, Soetaredjo, Felycia Edi, Ismadji, Suryadi and Ayucitra, Aning (2016) Synthesis, characterization, thermodynamics and biological studies of binary and ternary complexes including some divalent metal ions, 2, 3-dihydroxybenzoic acid and N-acetylcysteine. Journal of the Taiwan Institute of Chemical Engineers, 68. pp. 23-30. ISSN 1876-1070
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Abstract
The binary complexes with the [M(Dhba)] – core and ternary complexes with [M(Dhba)(Nac)] 3 − core have been synthesized and characterized by physical and spectral analyses, where M is divalent metal(Mn2+,Co2+,Ni2+,Cu2+orZn2+)and Dhba and Nac are 2,3-dihydroxybenzoic acid and N-acetylcysteine, respectively. The synthesized complexes are practical in biological applications Since they are soluble in water. The synthesized complexes were found to possess enhanced Antimicrobial activity, especially against Staphylococcus aureus, but reduced DPPH scavenging Activity of Dhba. The binary and ternary complexes of Zn2+were shown to possess the most Remarkable properties thus their structures were further examined. Thermodynamic properties Of theZn2+complexes in aqueous solution at various temperatures were also determined With an ionic strength of 0.15 mol/dm3 Na Cl. Keywords: 2,3-Dihydroxybenzoic acid Acetylcysteine Divalent metal Complex synthesis Metal–ligand Thermodynamic
Item Type: | Article |
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Uncontrolled Keywords: | 2,3-Dihydroxybenzoic acid Acetylcysteine Divalent metal Complex synthesis Metal–ligand Thermodynamic |
Subjects: | Engineering > Chemical Engineering |
Divisions: | Faculty of Engineering > Chemical Engineering Study Program |
Depositing User: | Felycia Edi Soetaredjo |
Date Deposited: | 17 Jul 2017 08:27 |
Last Modified: | 23 Jan 2024 09:53 |
URI: | http://repository.ukwms.ac.id/id/eprint/11041 |
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