Preparation of nanocrystalline cellulose-montmorillonite composite via thermal radiation for liquid-phase adsorption

Santoso, Shella Permatasari, Laysandra, Livy, Putro, Jindra Nyoo, Lie, Jenni, Soetaredjo, Felycia Edi, Ismadji, Suryadi, Ayucitra, Aning and Ju, Yi Hsu (2017) Preparation of nanocrystalline cellulose-montmorillonite composite via thermal radiation for liquid-phase adsorption. Journal of Molecular Liquids, 233. 29- 37. ISSN 0167-7322

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Abstract

Nanocrystalline cellulose (NCC) is an excellent binding agent used in various kinds of manufactures. Herein, NCC was used as a binding agent for montmorillonite (MMT) clay before producing composite (NcMMT), which will be utilized as an adsorbent for methylene blue. The morphology of the composite was investigated by using field emission–scanning electron microscopy (FE-SEM)and transmission electron microscopy(TEM), while the characterization was conducted by using Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). Two adsorption isotherm models, Freundlich and Langmuir models were used to evaluate the adsorption equilibrium. Adsorption kinetics was assessed by using pseudo-first and second order models. The result indicates that NcMMT is better adsorbent than MMT and NCC; as evidenced by the adsorption capacity (Qm) which is 183.8, 140.6 and 96.8 mg/g (at 60 °C) for NcMMT, MMT, and NCC, respectively. The adsorption kinetics was more reasonable described by the pseudo second order.

Item Type: Article
Uncontrolled Keywords: Adsorption Composite Montmorillonite Nanocrystalline cellulose Methylene blue
Subjects: Engineering > Chemical Engineering
Divisions: Faculty of Engineering > Chemical Engineering Study Program
Depositing User: Felycia Edi Soetaredjo
Date Deposited: 17 Jul 2017 08:37
Last Modified: 24 Jan 2024 02:45
URI: http://repository.ukwms.ac.id/id/eprint/11163

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